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All you need to know about pool water pH

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Written by Florence Dethier
Updated over 3 months ago

1. What is pH and why is it important?

The pH (or hydrogen potential) measures the acidity or basicity of an aqueous solution on a scale of 0 to 14. At pH = 7, water is neutral; at pH < 7, it is acidic; and at pH > 7, it is basic. French legislation stipulates a pH of between 6.9 and 8.2 for pool water, but the optimum value depends on the type of treatment used.

  • If treated with chlorine: Chlorine acts in the form of hypochlorous acid (𝐻𝑂𝐢𝑙), which dissociates into ions according to the reaction 𝐻𝑂𝐢𝑙 β‡Œ 𝐻⁺ + 𝐢𝑙𝑂-. The higher the pH, the more chlorine is transformed into 𝐢𝑙𝑂- ions, which are much less effective as disinfectants. Conversely, if the pH is too low, active chlorine can be wasted. The ideal range is around 7.5 to maximize its effectiveness.

  • If treated with bromine: Bromine acts as hypobromous acid (π»π‘‚π΅π‘Ÿ), which dissociates in a similar reaction (π»π‘‚π΅π‘Ÿ β‡Œ 𝐻⁺ + π΅π‘Ÿπ‘‚-). However, bromine remains effective over a wider pH range than chlorine. Ideally, the pH should be maintained at around 7.8 for a bromine treatment.

2. How to correct water pH?

  • To raise the pH: pH+ products generally contain sodium carbonate, or soda ash. When added to water, this product triggers an acid-base reaction with carbonic acid, releasing ions that raise the pH.

  • To lower pH: pH- products are often based on sodium hydrogen sulfate. When dissolved, they trigger a reaction involving the hydrogensulfate ion, which lowers the pH of the water.

3. What are the risks of an unbalanced pH?

An unbalanced pH can have a number of consequences:

  • pH too low (<6.9): corrosive water, irritation for bathers, accelerated wear and tear on equipment.

  • pH too high (>8.2): Ineffective disinfection, limescale deposits, cloudy water and discomfort for bathers.

4. To sum up: how to maintain an ideal pH?

For a healthy pool, test the pH regularly and adjust it according to your needs:

  • Chlorine treatment: ideal pH around 7.5.

  • Bromine treatment: ideal pH around 7.8.

A well-managed pH ensures effective disinfection and pleasant water for bathers!

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