Go to the technician's profile.

You can enter either a flat or a rate commission. The flat is the dollar amount you pay per job that the technician completes. They will get paid even if the job price is $0. The rate commission is a percentage of the job price, so they don't get paid on jobs that are free. You put a decimal (.1) instead of a whole number (10) for the percentage, so .1 would be the entry for a 10% commission.
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You will then be able to see how much to pay that technician over a selected date range from the technician report.

You can override a technician's default commission by changing the job or account commission.

You can change the Job Commission from a couple different areas:

   2. Process: 

Regardless of which technician performs this job, they will be qualify for commissions based on the job commission instead of their normal commission.

The technician that performs a job for an account that has an account commission will qualify for commissions based on the account commission instead of their normal commission.

In the scenario where a technician has a personal commission, the account has a commission, and a job for that account has a commission attached, the job commission will take priority.
In terms of priority, technician commission<account commission<job commission.